decatungstodivanadogermanic heteropoly acid (h6gew10v2o40.22h2o): a green and reusable heterogeneous catalyst for the synthesis of biginelli-type 3,4-dihydropyrimidin-2-(1h)-ones/thiones
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abstract
decatungstodivanadogermanic acid (h6gew10v2o40.22h2o) was used as a green heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1h)-ones from one-pot three-component cyclocondensation reaction of a β-ketoester, an aldehyde and urea/thiourea under solvent-free conditions is reported. this method provides an efficient and much improved modification of the original biginelli reaction reported in 1893, in terms of high yields, and short reaction times. it has the ability to allow a wide variety of substitutions in all three components.
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Decatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A green and reusable heterogeneous catalyst for the synthesis of Biginelli-type 3,4-dihydropyrimidin-2-(1H)-ones/thiones
Decatungstodivanadogermanic acid (H6GeW10V2O40.22H2O) was used as a green heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones from one-pot three-component cyclocondensation reaction of a β-ketoester, an aldehyde and urea/thiourea under solvent-free conditions is reported. This method provides an efficient and much improved modification of the original Biginelli reaction...
full textDecatungstodivanadogermanic heteropoly acid (H6GeW10V2O40.22H2O): A green and reusable heterogeneous catalyst for the synthesis of Biginelli-type 3,4-dihydropyrimidin-2-(1H)-ones/thiones
Decatungstodivanadogermanic acid (H6GeW10V2O40.22H2O) was used as a green heterogeneous catalyst for the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones from one-pot three-component cyclocondensation reaction of a β-ketoester, an aldehyde and urea/thiourea under solvent-free conditions is reported. This method provides an efficient and much improved modification of the original Biginelli reaction...
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full textCdS nanoparticles: An efficient, clean and reusable heterogeneous catalyst for one-pot procedure for synthesis of 3,4-Dihydropyrimidin-2(1H)-ones in solvent-free conditions
3,4-Dihydropyrimidinones and their derivatives are synthesized via Biginelli routes involving an aromatic aldehydes, ethylacetoacetates and urea in one-pot procedure by using CdS nanoparticles as efficient heterogeneous catalyst in solvent-free conditions. Compared with classical Biginelli reaction reported in 1893, this new method provides much improved modification in terms of simplicity. The...
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Journal title:
iranian journal of catalysisPublisher: islamic azad university, shahreza branch
ISSN 2252-0236
volume 3
issue 4 2013
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